What Are the Snowflake-Like Galvanized Metal Patterns in My Anodized Aluminum?

Those Are Grain Boundaries—Part of the Material

By Ed Rubin

IMG_3265Have you ever experienced the appearance of “raindrops,” “snowflakes,” or galvanized metal patterns in your anodized finish? If so, don’t shoot your anodize supplier. Let me tell you why. Common metals, such as aluminum, are polycrystalline in nature. These crystals are generally referred to as grains. The grains vary in size and shape and are defined by the edges of the crystal. They are commonly described as grain boundaries.

How to Tell if Your Product Has a Grain Boundary Pattern

  • Does the defect resemble either of the photos included in this blog post?
  • Does the pattern remain when the anodize coating is stripped?
  • Does the condition worsen when the part is re-anodized?

If the answer is yes to any of the above questions, it is likely that what you are seeing are grain boundaries. The crystal patterns that resemble frost on a window pane or galvanized steel most often are not visible on fabricated products such as rolled sheet or machined parts. However, when exposed to cleaning etchants that are used during the pre-treatment process followed by the anodize operation, the grains become visible.

IMG_3267There are two reasons that the boundary grains become visible:

  1. Etchants preferentially attack the material at the grain boundaries. This action creates contrast between the boundaries and the grains themselves, and thus, gives definition and contrast to the surface.
  2. The anodizing process itself has the same effect by consuming more material at the boundaries than at the grain proper. Very often it is the combination of the two that causes the effect to be visible.

Can this Problem Be Fixed?


Because the grains are produced during the heating, cooling, and mechanical processing of the metal, they become an inherent characteristic of the material. Once the grains become apparent, they are very difficult to hide. The metal finisher has limited ability to mitigate this cosmetic appearance. Sometimes applying a new mechanical finish can hide the issue. Good heat-treating practice will measurably reduce this occurrence. What we can do is advise you on how to minimize this effect if it should appear.

It is important to note that both the size and shape of the grains is created by the thermal and mechanical history of the metal and becomes an integral part of its properties. Heating followed by slow cooling tends to produce grains with large cross sections. Examples of this can be found in castings, extrusions with large cross sections, and heat-treating with no quenching. Smaller grains are produced during mechanical processing, as well as tempering. Examples of these are forging, rolling, and heat treatment followed by quenching. Extruded shapes having both thick and thin cross sections may simultaneously contain both large and small grains.

At DCHN, we know that many questions arise when considering aluminum anodizing, hardcoat, and other metal finishing jobs. Our white paper, “12 Proven Tips to Save Time & Money for Aluminum Anodizing, Hardcoat, and Other Metal Finishing Services,” is a guide full of great tips to help you save time and money. Download it now.

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Resource Considerations when Anodizing Aluminum

Aluminum Anodizing and Water Conservation Do Not Have to Be Incompatible
Water-Conservation-web

In my day, in metal finishing class 101, the first thing you were taught about aluminum anodizing was this: when you think you have rinsed enough, rinse again. Clean water is your friend; use it. That was great advice when water was free, or nearly free—and it still holds true in aluminum anodizing—but increasingly difficult and expensive, not to mention environmentally inconsiderate.

Today, water is no longer inexpensive. In fact, at DCHN, water is our second most expensive utility. And this from an aluminum anodizing company that heats 2,000 gallon tanks with natural gas and powers all our rectifiers, (big electricity users) pumps, chillers, compressors etc. with electricity. Water not only has to be paid for on incoming, but it also has to be treated at our cost to clean it and then paid for again to go to sewer— and that rate is nearly equal to incoming.

The easy thing to do would be to pass these expenses on to our customers—but what does that solve?

Conserving Resources Resourcefully

How, then, does a metal finisher conserve water and still provide the high-quality finish expected by customers? The answers are simple, but not easy or cheap. There are many water recycling units available and many methods of counter flow rinsing that will help reduce water usage. Training of operators and filtering also help keep water clean. These details are not as important as the idea that using less water is good for everyone. Expense aside, the conservation of water is an environmentally sound thing to do and is requisite to becoming a green-minded company.

DCHN has begun an aggressive campaign to reduce water usage and create alternative methods of conservation. Responsible stewardship and helping future generations enjoy a clean world with plenty of resources is one more benefit we proudly offer our customers and the greater community.

At DCHN, we know that many questions arise when considering aluminum anodizing, hardcoat, and other metal finishing jobs. Our white paper, “12 Proven Tips to Save Time & Money for Aluminum Anodizing, Hardcoat, and Other Metal Finishing Services,” is a guide full of great tips to help you save time and money. Download it now.

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10 Questions to Ask Reputable Anodizers

How Do You Chose the Right Anodize Company?

How-to-Chose-Anodize_dchn_coated_partsChoosing any vendor, for any service, can be a challenge if it is done correctly. I posed my industries’ problem to a professional procurement VP and former metal finishing buyer. “Buying services can seem simple,” according to the VP of procurement for a major orthopedic company. “In fact, it’s often much harder than buying a tangible product.”

I was fortunate enough to have similar conversations with many such talented people and took away some great thoughts from these discussions. My intent here is to shed some light on the difficulty and misconceptions when choosing an anodize vendor. We are all buyers. Every one of us purchases services and products and we have thought patterns when doing so that allow us to make decisions that suit our needs. Usually, the three biggest items regard quality, service and delivery, and price—followed by smaller, but important items like, convenience, reliability, trustworthiness, and many others. Let’s look at a few seemingly small purchases made in some, if not most, of our lives.

You want to buy a service for, let’s say, landscaping. You find a company local that seems okay. Do you just hire them and see how it goes? Typically not. You usually ask a host of questions, something like this:

  • How long have they have been in business?
  • Where can you see their work or get referrals or testimonials?
  • Are they a contemporary and viable business?
  • How reliable are they?
  • Are they trustworthy?
  • Will they be around next year?

My guess is that these are just some of the questions that will run through your mind. If all your questions were answered satisfactorily, what was the first thing you thought of after that? It’s generally about the price. If it was price, that begets another whole set of considerations. If the price was right for you, did all the other questions not matter? If the hedges aren’t even and the lawn has been fertilized in stripes, is that okay if it’s cheap? Again, my guess is that the answer is no. What if the price was too high? Is that a showstopper? BUT, what if the price was great and everything looked great, but after hiring them, corners were cut that you couldn’t see? Suppose there was poor insect control, bad lawn feed, flower care, etc. Maybe not this year, but the consequences of that will show eventually. Would it be worth it? I can think of many examples: think about a house painter who doesn’t scrape well, uses poor quality paint, no primer, and paints over items that should be removed or masked. It looks good today, but soon it will not. How about a car mechanic who uses poor quality parts, does “patch it” repairs, or worse, creates a new problem by using a poor product or method? I think you get the idea.

I’m using these examples to illustrate a point. It’s pretty much a daily occurrence that we make buying decisions or are at least in the consideration phases. These decisions can have lasting impact and can save or cost us money; some seem like such obvious choices. However, they are not all obvious. Truth is, everyone wants quality—and if the perception is that all the vendors provide the same quality, then the usually considered variables are price and delivery.

Let’s take a closer look at the mechanic. Your car was repaired in a day—perfect. The bill was reasonable—that’s great. Your car runs fine for three months … and then, wham! Back in the shop for more repairs. My guess is that it won’t go back to the same mechanic, because you lost faith (aka trust) in him and now know the quality of his work is suspect. But what if you sold that car after three months and the breakdown was on someone else’s dime? Does that matter? Would you still think the decision a good one? That’s a harder question, but none the less, speaks to the point of this blog.

Often, I hear from customers that all anodizers are alike and produce similar quality because when the customer (you) gets the parts back, the only judgement on quality is “how does it look?” If they look good, it’s fine. Remember the house painter? The house looked great, but peeled in a year or less. The problem here is that most buyers of anodized product do not know how to judge quality. It’s not their fault, and it’s not a knock on buyers because often, quality assurance people aren’t sure how to judge quality on anodized products. There is confusion on what to test for to see if they have a good product. Once in the field, poor anodize performance is seldom reported, and often, the field people think this is what is supposed to happen to anodize after a year or two. Again, lack of knowledge about what makes a good anodic coatings is to blame.

Given the examples above, I believe it is critical and smart to understand how to choose a good anodize vendor.

10 Considerations for Choosing a Reputable Anodize Vendor:

  • First, ask about any accreditations they have—that is: are they ISO 9001 registered, etc.?
  • If they provide certs, can they prove that they have submitted their test panels monthly and passed? Passing qualifies them to issue certs.
  • Inquire if they belong to any anodize organizations where they will be kept apprised of new technology.
  • Find out what type of anodizing they perform: type II or type II and III, etc.
  • If they do type III, how do they process the parts: by current density or voltage?
  • Do they know how to effect hardness?
  • Ask about the type of chemistry controls they have in place.
  • Ask if they have a reliable system of recording chemical titrations and additions.
  • Inquire about quality controls: Do they measure, have on-time delivery, customer return rates, first-pass yield, and other quality metrics?

There are many other things that can be asked of your anodize vendor or one you are considering. The bottom line is, if they do not have a good quality system and control and measure their performance and output then maybe there are other things that go uncontrolled or unmeasured. Choose wisely.

I hope that this offers guidance on the issues that I see as a long standing member of the anodize community and a person who works within that community to advocate for the industry and its customers.

At DCHN, we know that many questions arise when considering aluminum anodizing, hardcoat, and other metal finishing jobs. Our white paper, “12 Proven Tips to Save Time & Money for Aluminum Anodizing, Hardcoat, and Other Metal Finishing Services,” is a guide full of great tips to help you save time and money. Download it now.

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Medical Anodizing Applications at the World Congress on Aluminum DCHN Presented the MICRALOX Solution

In 2011, with the patent pending technology MICRALOX®, just newly announced and as of yet unknown, I was asked to speak at the World Congress on Aluminum in Bologna, Italy. That conference so peaked my interest in this world-wide attended event that I jumped at the chance to discuss this technology when invited to speak in 2015 at the 9th World Congress on Aluminum, “Aluminum Two Thousand,” in Florence, Italy, as it relates to medical anodizing applications. I presented a technical paper, “Anodizing for Medical Applications,” covering the present state of anodizing performance on reusable medical devices and instruments, problems relevant to anodized aluminum parts, key challenges driving the medical device industry to search for other alternatives to aluminum, general considerations on the unique properties of aluminum, and introduced DCNH’s micro-crystalline anodic coating solution, MICRALOX.

Logo_testata

The congress was held in Florence Italy from May 12 thruogh14. The three-day meeting was full of both new technology papers and information on improvements to established methodologies, as well as presenting multiple commercial opportunities. Joining the congress was the International Conference on Extrusion and Benchmark (ICEB), which helped elevate this conference to a more well-rounded and aluminum-focused audience.

The opening speakers at the conference caused immediately reaction from the attendees, who described the first morning as a boost for aluminum suppliers and aluminum finishers alike. The tone of the opening speakers was a positive and forward-looking perspective of the potential opportunities which lie ahead for those in this industry. Since the congress then split into several “focus sections,” my observations of the content became more difficult to judge. However, based on the technical papers I observed, the congress was well represented by subject-matter experts who lent their knowledge to the audience.

Italy_attendees_4_FullSizeRender (2)Aluminum continues to be one of the most utilized and sought-after materials for products being developed due to the many positive properties it possesses. The information shared at the conference gave those of us professionally connected to this material a sense of pride and a positive outlook on the future of the use of this versatile metal.

Aluminum 2000 was attended by representatives from 46 countries, which showed the importance of this type of event to the world community.

The importance of new technology, such as MICRALOX, is promoted and heralded by the congress which promotes itself as the leading proponent of aluminum and aluminum finishing technology. It appears to be an accurate assessment based on this man’s observations.

New technology aside, the conference afforded a great opportunity to connect with peers and meet the up-and-coming leaders of the industry. Given the growth of aluminum usage in the world community, the chance to be on the ground floor of developments is an opportunity that should not be overlooked.

Sanford Process Corporation and DCHN were honored to be part of this event and more honored to be considered a world-leader in medical anodizing technology. If asked again, we will be there to advance the aluminum anodizing industry and speak for the support of new technology and advancement of the industry at large.

As the largest aluminum anodizing and hard-coater on the East Coast of the United States, DCHN has a broad range of production capabilities, starting at lab testing, to pilot and development, through production. Each production line has a wide variety of capabilities to produce anodic coatings exactly to our customers’ diverse and challenging specifications. DCHN operates one of the newest and most complete production line capabilities in the country.

We know that many questions arise when considering aluminum anodizing, hardcoat, and other metal finishing jobs. Our white paper, “12 Proven Tips to Save Time & Money for Aluminum Anodizing, Hardcoat, and Other Metal Finishing Services,” is a guide full of great tips to help you save time and money. Download it now.

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White Specs on Sharp Edges of Type II & III Aluminum Anodizing

What to Know About Knurls and Graining

White Specs on Sharp Edges of Type II & III Aluminum Anodizing

Sample of white-spec and knurling problems associated with anodizing, supplied by DCHN Metal Finishing Services

You’ve made your parts and shipped them off for finishing. Seemingly an easy request. Then you get your part back from the anodizing company and you see these whitish looking specs along the edge of your part, or maybe in the knurl, or just randomly scattered along a grained finish. You know the condition is unacceptable and your immediate thought is that the aluminum finishing is inferior or the anodizing company did not do the job correctly. Are those correct assumptions?

It’s Common, Simple … and Complicated

Sharp edges and the treatment of them is a common problem faced by both customers and their anodizing service. While this seems like a simple issue, it can be quite vexing. The problem is, indeed, simple. Anodic coatings cannot form where there is no aluminum. Aluminum oxide forms perpendicular to the surface. A round or radius object is easily anodized because there is a continual supply of aluminum to convert into oxide. However, a sharp edge, 90-degree bend, a knurl or top of a grain line are not conducive to the formation of aluminum oxide. Since the coating does grow perpendicular, a sharp edge simply cannot supply the aluminum it takes to grow the coating. And the thicker the coating requirement, the more difficult the problem. As the coating forms, it needs a steady supply of aluminum to continue thickness growth. If aluminum is not present, the coating will stop, but worse, it will deteriorate and/or break off and separate. The result is an area with voids or “white spots.” This, of course, is exacerbated if the coating is dyed—these spots become more visible set against a colored backdrop.

The Fix

The best remedy to correct this condition is to round any edges or at least remove any hanging sharp edges or burrs. On knurls, this can be done by a polishing, buffing, abrasive wheel bead blasting or tumbling. Edges should be given a radius whenever possible and formulas exist for coating thickness vs. radius, and graining should be followed by a light surface buff to remove the sharpness, or simply use a less aggressive coarseness belt or paper.

The anodizing company can use chemical means to etch the edges, but remember that ALL dimensions will be affected by the removal of aluminum and it can result in dimensionally out-of-spec parts. Therein lies the rub for the anodizing service. If they treat the part to mitigate the condition, they may ruin the part dimensionally. When given this choice, the aluminum finishing company simply must process the part hoping that the sharp edges aren’t too sharp. Unfortunately, this isn’t known until the parts are completed—and it may prove to be too late.

The best result is obtained when the manufacturer understands this and mitigates these conditions by supplying a part that is anodize-ready.

DCHN can help you understand more about sharp edges and their effect on quality. We know that many questions arise when considering aluminum anodizing, hardcoat, and other metal finishing jobs. Our white paper, “12 Proven Tips to Save Time & Money for Aluminum Anodizing, Hardcoat, and Other Metal Finishing Services,” is a guide full of great tips to help you save time and money. Download it now.

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Pursuing Color Match vs. Color Range when Anodizing Colors

ano_type2Important Distinctions for Achieving Desired Outcomes when Color Anodizing

Aluminum anodizing, whether it is type II or type III, is achieved by electro-chemical methods prescribed and designed to yield oxide coatings with certain properties. These properties can be hardness, thickness, electrical resistance, corrosion resistance, bond-ability, lubricity, and/or combinations of several of the above. One common, desirable output of aluminum anodizing is the ability to obtain color on the part—for both type II or type III. When anodizing colors, there is a distinction between color range versus color match. Let’s explore the variables that are behind this.

You may have heard that the most common method of color anodizing is achieved by submersing anodized parts into a dye bath to create the color. The dye absorbs into the open pores that are created during the anodic coating process and then they are sealed to help keep the color in for as long as possible. However, even if the dye is the hue you want to achieve, there are many variables that can affect the outcome of the final product. Even under the tightest of anodize controls and the strictest chemistry ranges, these variables can cause enough differences to make exact color matching a nightmare.

True” Color Range?

Truth is, anodizers face complex issues when attempting color match and repeatability. This is why “color range” is so important when deciding what is acceptable and what can be achieved repeatedly. Remember, color is achieved by dye absorption, and since it is being accomplished while “underwater,” where it can’t be seen, it is impossible to hit an exact match every time. Given the many variables such as alloy, type of anodic coating, rate of dye absorption, pore size, coating thickness, and color displacement during sealing, to name just a few, anodize color repeatability is understandably difficult.

One more fact to consider when anodizing colors: the “color” is not achieved by applying a pre-mix solution that lies on an object that it contacts and then dries, such as paint. Rather, it is the result of a combination of chemical steps designed and controlled to give performance attributes and allow the best chance of color success.

Variables Vary

The hard facts are that good color matching and repeatability are directly connected to tight control of all possible variables, full understanding of how these variables interact and affect the end color, and an educated customer who understands that desired performance criteria such as, hardness, thickness, type of anodizing requested, etc. may be in conflict with achieving the desired color.

Ask us about how we can best deliver an acceptable and consistent color to you through our color anodizing. At DCHN, we know that many questions arise when considering aluminum anodizing, hardcoat, and other metal finishing jobs. Our white paper, “12 Proven Tips to Save Time & Money for Aluminum Anodizing, Hardcoat, and Other Metal Finishing Services,” is a guide full of great tips to help you save time and money. Download it now.

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Anodize Sealing and RoHS Compliancy Nickel Fluoride Bath Solution

dchn_anodize_general_blogThe formation of the anodized coating on aluminum is characterized by a series of closely packed hexagonal columns with a cylindrical type pore in the center of each column. The significance of the pore during the anodizing process is to allow electrolyte to flow to the aluminum surface and to provide a path for ions to flow and allow the anodizing process to proceed.

After the anodizing process, these pores also act as a receptacle for dyestuffs should they be desired. These pores, however, can also act as a conduit for corrosion processes in many circumstances. In most cases, these pores are closed in the final stage of the anodizing process during the “sealing” step.

The Sealing Step

This sealing step can be accomplished using a variety of agents. The simplest is boiling deionized water. This is, however, a slow process and is presently only used in limited applications. A more common agent—and the one most frequently used—is a hot, 180° to 205°F solution of nickel acetate. This method is favored in conventional (i.e. not hard coat) anodized components that have been colored with dyes.

The sealing of hard coated (hard anodized) surfaces is more problematic. While hot sealing significantly reduces the potential for corrosion, it also measurably lowers the hardness of the coating.

Hard Coat Sealing Alternatives

dchn_hexagonal_coatingAn alternative commonly employed for hard coatings is to use a solution of either sodium or potassium dichromate in lieu of the nickel acetate bath previously discussed. The advantage of this bath is that it is operated at a lower temperature and provides good corrosion protection. A disadvantage is that the dichromate tends to leach from the film over time. This causes a gradual loss of corrosion protection. To help mitigate this problem a “duplex” seal was developed, which combines the nickel acetate and the dichromate processes. This method reduces the migration of the dichromate from the coating, but also somewhat decreases the hardness of the hard anodized surface. In most applications, this “compromise” has been acceptable and provides a corrosion resistant and reasonably hard coating.

Alternative Solution

However, the use of hexavalent chromium has been under scrutiny and within the RoHS guidelines has been banned. Fortunately, there is an alternative sealing method that provides very good corrosion protection without decreasing the hardness of the coating. This bath utilizes nickel fluoride at or near room temperature and is used extensively at the D-CHN facilities.

While the use of the dichromate process would help with corrosion protection, the low-temperature nickel fluoride seal will provide excellent corrosion protection while preserving the hardness of the hard coated surface, keeping the product RoHS compliant.

We know that many questions arise when considering aluminum anodizing, hardcoat, and other metal finishing jobs. Our white paper, “12 Proven Tips to Save Time & Money for Aluminum Anodizing, Hardcoat, and Other Metal Finishing Services,” is a guide full of great tips to help you save time and money. Download it now.

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Top 16 Questions about Masking Anodized Aluminum

Expert Answers to Masking Requirements for Anodized Aluminum Parts!

dchn_maskingThere’s much to consider when designing your aluminum parts to be anodized. If your parts require it, masking can be a crucial step in the process to ensure they are finished in accordance with the engineering specifications. We sat down with Bobby Scott who joined the precursor to DCHN in 1967 to share his knowledge and experience over thousands and thousands of jobs over these many years. An expert in our masking department, he knows the anodizing and masking processes inside and out. We want to share with you some of his experience.

1.) What is masking and why might you require it for your anodized aluminum part?

In anodizing, if a customer needs electrical contact on an aluminum part, or if the anodic coating may cause dimensional issues, we mask the specific area to avoid coating these surfaces during the tank operations. It is extremely important to have the right masking in the right places in order for the product to function the way it should, according to the engineering requirements specified by the customer.

There are several reasons to mask. As stated, one primary reason is that you don’t want to create anodic coating in those areas where electrical contact is needed. Anodic hard coat acts as an insulator, preventing a good current flow across the coated area. Uncoated aluminum is a good conductor of electricity, so when you mask an area so that it will not receive hard coat, you allow the aluminum’s inherent conductivity to continue.

2.) Where are some of the areas you don’t want to see or build dimension?

Controlling dimension is critical in a number of areas, including threaded holes and also in areas where parts may fit together. Contact areas are sometimes left uncoated to achieve precise fit. The masking of these areas needs to be precise for parts to fit well together and achieve the desired outcome.

3.) In areas where you need contact, why is a part left uncoated?

With many parts that we anodize, we don’t get to see how it is used. If we know where it fits and what it looks like in the finished process, we have a better understanding why it is done that way, and what the critical requirements are. It’s often because the end-user will be using the part it in an environment that requires discharging static electricity so they need electrical contact, but we commonly don’t know what the ultimate use of a part will be.

4.) What techniques are used in masking?

We use many types of masking. For instance, we use a combination of rubber and plastic plugs and gaskets. We also use various specialty types of tape and other adhesive-backed materials. We use different masking, depending on the requirement and also the type of anodizing process that is requested, which is very important. Sometimes we use fixtures in several different ways. It depends on the specifications of the job—customers’ demands on coating dimensions, what the part looks like, and how the areas coincide with one another.

5.) What determines which masking technique to use?

The choices are many and the reasons can be complex. Surface condition of the part, accessibility to the area to be masked, coating thickness, and the chosen anodizing type itself are all important factors.

6.) What are some of the problems to overcome?

Certain edges present challenges. Outside edges in general give you a better, neater, and a more accurate mask—as opposed to masking on an inside corner. It is very difficult to get a straight clean line or a neat looking mask when masking an inside corner.

7.) Do you have to work with the customer upfront to design the part, from an anodizing and finishing perspective, to help get a good quality product?

If we can have a dialog with the customer about needs and expectations and have knowledge about what is acceptable and what is optional, it is extremely helpful. We need precise information, such as masking blueprints to tell us exactly what is involved. Written notes from customers are preferred over verbal instructions, if there are any special requests. The issue around design is that in nearly 100% of the cases, the finisher is not brought into the discussion, which often could have helped make the part easier and cheaper to coat.

8.) When we talk about edge, if you have a 90-degree edge—is it easier or harder to mask than a beveled edge?

It is harder with a beveled edge. You can still mask the same way with a beveled edge, but there is more free-hand masking involved. The end result is that it may not produce as clean a line as a sharp edge. The problem with too sharp an edge, however, is that you do not form a coating on a sharp angle, as the coating grows perpendicular to the surface; and this can lead to “edge-effect.” Also, a sharp edge is more prone to chipping when impacted.

9.) What about texture—if it is more grained finish versus less grained—does that matter?

The part that has a somewhat rougher surface would provide a better surface for the adhesion of the masking material. It’s more difficult to get masking to adhere to a surface that is very shiny or polished. All else being equal, when it’s a mirror surface, the masking materials get less adhesion; and there is more chance of adhesion failure during the process.

10.) Does alloy matter?

Not in general, but castings can offer a cleaning challenge when masking is needed.

11.) Does size matter?

In general no. However, it depends on the equipment that a particular finisher has at their disposal.

12.) What about ID size?

Obviously, if you have to selectively mask an ID, you have to be able to reach it. If you need to keep an ID uncoated, you can plug or cap the ends of the ID so that the electrolyte doesn’t go inside and form the coating. If you have an ID that you are selectively masking—that is, you want to have coating in certain areas and not in others—you actually have to able to reach it because you are putting a mask in the area usually by hand. So you need to be able to touch the area to selectively mask it.

13.) Does color versus natural hard coat matter?

No, not really.

14.) What about temperature?

I assume you mean temperature during the coating process. The biggest concern for any part being masked is temperature. The anodic process includes steps with many different temperatures. Many tanks run hot (and some cold), and it can effect or lift the mask to some extent under certain conditions. If the mask needs to be perfect, we need to choose the masking technique carefully for the finishing process to create the desired results. Sometimes the two needs clash because the coating temperatures are critical to achieve the functionality and masking materials don’t always allow both chemical AND temperature resistance. Often our choices are limited.

15.) How do you mask threads?

If it is an inside thread, we can usually use plugs or threaded rod or bolts in most places. When we can’t use a plug, then we can generally paint mask a thread—though it needs to be a dissolvable masking type, so that we can completely remove the masking from the thread afterwards.

16.) When you don’t anodize or hard coat an area, how do you finish it? Or do you?

When allowed, we often use yellow and clear iridite or chromate as a base. These coatings are used for corrosion resistance and paint adhesion in many applications. We can use the iridite or chromate process after the anodizing process is complete and the masking is removed, if the customer wants protection or prior to masking.

We know that many questions arise when considering aluminum anodizing, hard coat, and other metal finishing jobs. Our white paper, “12 Proven Tips to Save Time & Money for Aluminum Anodizing, Hardcoat, and Other Metal Finishing Services,” is a guide full of great tips to help you save time and money.

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Eliminating Grain Exposure in Aluminum Anodizing What’s Behind Coring and Alligator Skin on Anodic Coatings

“What is this? The part was processed and returned and I took one look and said, ‘How did you guys cause this issue?’” This was a question from one customer, but is voiced from time to time in the industry. His confusion at seeing product with coring returning from the anodic coating process came from not understanding that the grain boundaries on some aluminum alloys can show themselves when the metal is prepared for anodic coating.

Customer’s Perspective
Eliminating Grain Exposure in Aluminum AnodizingThe customer’s assumption was that we etched too much or that we had contaminated tanks or that we stained the parts by poor rinsing; anything, but not the aluminum. How could it be the aluminum? The parts look great upon leaving their building and the aluminum manufacturer had specifications and certification to prove everything was perfect! Then why did these parts look as they did when returned?

In this case, the aluminum was made from round stock of 6061 alloy. The parts were sliced from the bar and machined to dimensional specifications. They had great cosmetics and were sent in as-is from the machining operation. The “simple” task of anodizing should have yielded perfect parts. Then why was coring present in this customer’s material?

Simple Chemistry
It’s simple. Aluminum is dissolved and transformed into aluminum oxide through an electro-chemical process. The anodic coating operation inherently consumes aluminum as it forms aluminum oxide. This process will dissolve aluminum from the surface inward. As it does, it can expose the grain boundaries that are formed by differential cooling rates from outside to inside. Inside grain boundaries are referred to as coring. These will exhibit themselves, if present, if the aluminum is sliced like a piece of pepperoni. Outside grain boundaries have no name, but exhibit the same “alligator skin” or “fish scale” look as coring. This outside effect normally exhibits itself on the outer 1/16” to 1/4” of the round part as a scaly look. It is not necessarily on the very outside for various reasons, but rather just inside the OD.

Common Assumptions
These grain boundaries are not apparent before anodizing and they are not to be “assumed” present by the anodize supplier. Customers who buy stock do not know if this condition exists and usually do not understand why it is seen only AFTER anodizing. This isn’t to say that there is a plot by aluminum extruders to “hide” this information, because this issue is well documented and understood by them. The problem is that often distribution houses or suppliers may not be as well versed. Also, because certifications are supplied, it is assumed that all is well with the aluminum stock. The fact is that certifications only cover the metal make up and temper, but not necessarily manufacturing processes or cooling methods or results.

Easy Solution
So how can you avoid these issues? Well, one thing is to understand that they can exist and are more common in round stock. Then, the aluminum vendor can question the aluminum supplier/vendor and put them on alert that this condition will not be acceptable. If you have stock in your possession already, take a slice (or two) off the bar stock and send it to us so we can check for this condition before you manufacture parts.

If confronted with this issue, there are things that an anodizer can do to help prevent it from reappearing, but only after there is some mechanical remediation. For more information on this topic, please contact DCHN.

We know that many questions arise when considering aluminum anodizing, hardcoat, and other metal finishing jobs. Our white paper, “12 Proven Tips to Save Time & Money for Aluminum Anodizing, Hardcoat, and Other Metal Finishing Services,” is a guide full of great tips to help you save time and money.

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Metal Tolerance Guidelines as it Relates to Different Aluminum Hard Coat Technologies.

Insightful Guide to Quality Product for Metal Finishing Manufacturers  ~ By Jack Tetrault, President of Sanford Process Co. 

March 19, 2014, Woonsocket, RI

Regardless of how experienced the manufacturing company that buys hard coat or other anodic finishes on aluminum is, there seems to be misunderstandings about what they need to do to insure that their tolerances are held during the finishing operations. Often, I see the same assumptions made and the cost of these assumptions can be high. Considering just the coating thickness, without considering what tolerance the finisher needs or what material they need to remove to provide cosmetic appeal to the part can be the stake in the heart of a quality product. Click here to see our white paper on Metal Tolerance Guidelines as it Relates to Different Aluminum Hard Coat Technologies. This can save you many headaches.

© 2014 Jack Tetrault, Sanford Process Co., All Rights Reserved

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